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» ES bi heating with foamed glycerin. Review of heat transfer fluids (coolants) on various bases. Using glycerin as a coolant

ES bi heating with foamed glycerin. Review of heat transfer fluids (coolants) on various bases. Using glycerin as a coolant

Today, a fairly current trend in heating private houses is the abandonment of the use of classical methods in favor of alternative ones. In this case, quite often preference is given to autonomous heating systems filled with a special liquid solution. The variety of fillers is quite large, so it is important for consumers to choose the right coolant for specific conditions. After all, here it is necessary to take into account not only the cost, but also such important characteristics material, such as service life and operating conditions, viscosity, operating operating temperatures, heat capacity, environmental friendliness, safety, etc.

Glycerin-based coolant is quite popular because it is suitable for heating systems that meet all the above requirements. A very important factor is that the BIO coolant is universal and can be used to fill closed or open heating systems, and can also be used for air conditioning systems and other needs.

The glycerin coolant is considered very practical and easy to use; its main advantages include resistance to temperature fluctuations: the substance works effectively in the range of -30...+105°C. This property in case of breakdown heating equipment V winter period freely repair or replace it individual elements. At the same time, if the system stops, you don’t have to worry about its further safety, since, unlike water, the BIO coolant will not rupture the pipes when it freezes. The BIO coolant contains a special fluorescent dye, which makes it possible to easily detect where the system is damaged in the event of a leak.

The glycerin coolant is completely environmentally friendly and meets safety requirements, which is confirmed by the presence of the necessary certificates. Glycerin safety confirmed wide experience applications in other areas of human activity: in the food industry and medicine. The BIO coolant is a non-flammable material, which guarantees the explosion and fire safety of the system.

Also, the glycerin-based coolant contains special anti-foam and anti-corrosion additives, which allows the use of elements and devices made of a wide variety of structural materials in heating systems: steel, non-ferrous metals and their alloys, polypropylene, etc.

The glycerin-based coolant has a fairly long service life - it can be used for up to eight heating seasons. This indicator significantly reduces the total cost of filling the system, while increasing its durability. An additional advantage of such a substance is the guarantee of safe operation of circulation pumps. This antifreeze is completely inert to various types of gasket and sealing materials, without destroying them upon direct contact during the heating season.

Calculating the need for antifreeze is quite simple. Since the density of the BIO coolant is 1.13 kg/m³, to determine the amount of filler required for your system, you need to multiply its volume by the appropriate coefficient. For example, for a system with a volume of 100 liters you will need 113 kilograms of BIO coolant. Glycerin antifreeze is supplied in canisters weighing 10 and 20 kg and is ready for use. If you decide to purchase such products, then our company’s specialists will offer you not only sufficient volumes of BIO coolant, but will also advise you on its properties.

In the columns: Yellow - glycerin-based coolant, Green - propylene glycol-based coolant, Red - ethylene glycol-based coolant.

In the operating temperature range, the Warme Eco 30 coolant has a viscosity 3-5 times higher, which leads to the need to use more powerful circulation pumps (+10% in volume and +60% in pressure). Installing a more powerful pump eliminates the problem of overheating of heaters in electric boilers and heat exchangers in gas boilers, and also reduces the risk of additive decomposition when heated above 95 C. Warme Eco 30 coolant has a coefficient of thermal expansion greater than water, so it is necessary to install an expansion tank 20% larger than for water. The heat capacity and thermal conductivity of glycerin coolants is 15-20% less than that of water.

Advantage over propylene glycol-based coolant Warme Eco PRO - 30

(*) in price (20% lower), and glycerin coolants are not afraid of the presence of galvanized pipes in the system.

(*) Deleted.

COOLANTS.
Advantages and disadvantages various types.
Why you need to choose a coolant based on propylene glycol.

Coolants are conventionally divided into three groups: water, brines and antifreeze.

The most reliable, safe and modern coolants are products based on - propylene glycol. They have been used in the world for about – years. Germany, France, USA switched to using - propylene glycol coolants since – years, and then they began to be used in almost all European countries.

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In Russia, their share of the total volume of coolants sold is growing rapidly. At the state level, a ban has been introduced on the use of ethylene glycol coolants in refrigeration equipment and heating of railway cars.

WATER AS A COOLING CARRIER

Advantages Flaws
  • Environmentally friendly substance;
  • Has high heat capacity;
  • Easily circulates through the heating system;
  • Always at hand and can be quickly added to the heating system;
  • Low cost.

Water freezes in the system at temperatures below - °C and, as a result, disables the system / you cannot leave a house with the heating system turned off but full in winter /. In a matter of days and even hours, elements of the heating system / boiler; batteries; expansion tank; circulation pump/ will simply be torn apart.

Heating system corrosion. If, in order to avoid defrosting the heating system, the water is drained, corrosion processes in a system filled with air proceed even faster than in water.

The need to change the chemical composition of water before using it for heating. Natural water characterized by such an indicator as rigidity. At water temperatures above – °C, intensive decomposition of carbonate salts and scale deposition on the walls of the heat generator and pipes begin, which causes deterioration in heat transfer and failure of heating elements due to overheating. It is desirable that the water contains special additives that can extend the life of the heating system (corrosion inhibitors, etc.). Ideally, additives will be added to distilled water.

Adjustment of electrical resistivity of water during the heating season.

Carrying out annual system flushing and boiler repairs.

SOLUTIONS OF SOME INORGANIC AND ORGANIC SALTS

AS A COOLANT

Salt solutions, although they freeze at lower temperatures than water and are harmless to people, are highly corrosive. Over time, they “salt out” on the surface of pipes and heat exchangers. Such solutions also do not “cope” with Russian winter conditions due to insufficiently low freezing temperature.

Do not use ethyl/methyl alcohol or transformer oil as a coolant due to their high fire hazard.

At the present stage, antifreeze is increasingly used as coolants.

Antifreeze are low-freezing liquids used to cool internal combustion engines and various installations/including heating systems/ operating at temperatures below – °C.

COOLANT BASED ON GLYCEROL

Advantages Flaws
  • Environmentally and toxicologically safe. It is not dangerous even after prolonged inhalation of vapors and does not cause poisoning if accidentally ingested.*;
  • Unlike glycol coolants, it is inert towards galvanized parts. ** ;
  • Cheaper than propylene glycol based coolant.

Due to the higher density, the mass of glycerin coolant to fill a system of the same volume will be greater than the mass of glycol coolant, which will create an additional load on the equipment.

The viscosity of glycerin solutions, especially at low temperatures, is higher than glycol solutions; this accelerates the wear of some parts of the heating system, such as pumps and circulation pumps; the installation of more powerful pumps will be required.

At the same freezing point, glycerin coolant contains more organic component /glycerol/ and less water than glycols /propylene glycol, ethylene glycol/. This leads to an additional increase in density and viscosity and a decrease in heat capacity.

Glycerol is thermally unstable:

– with prolonged heating above – °C, it decomposes with the formation of volatile and carcinogenic substances, including acrolein. Decomposition products are also corrosive. When they polymerize, deposits form on the walls of the heating system, impairing heat removal and clogging the system.

– have a high freezing point. When water is completely evaporated from the coolant, the base freezes at + °C, and, often, at + °C.

Glycerin foams strongly, for this reason heat dissipation deteriorates and the risk of airing the system increases.

When aqueous solutions of glycerol are used as coolants, the requirements for gaskets/seals/ and parts made of non-polar rubbers and plastics are increased.

* – coolant that has not been used, and does not contain additional components except glycerin, water and an additive package.** – coolant based only on glycerin, without additives

Does not exist state standards /GOST/, establishing requirements for antifreeze/coolants based on glycerin. Such coolants are produced according to technical specifications in which product quality indicators are established by individual manufacturing companies.

Under the brand of glycerin-based coolants, there are also mixed coolants containing propylene glycol along with glycerin.

Currently, there is not a single major global or domestic manufacturer, which switched to the production of glycerin-based antifreezes and coolants.

The most reliable and proven coolants are those based on glycols.

COOLANT BASED ON ETHYLENE GLYCOL

Advantages Flaws
  • Protects the system from defrosting;
  • Good thermophysical properties;
  • Low levels of salt and scale deposits;
  • Average cost.
Ethylene glycol toxic, has a narcotic effect. It is absorbed into the body quickly.

The degree of harm that ethylene glycol causes to humans depends on the amount of poison, the method of penetration and the individual condition of the body.

If swallowed, pulmonary edema occurs and acute heart failure develops. Experts give different figures for the lethal dose of a substance: – mg per kg of weight; – ... mg per person. Mortality in acute poisoning is high - more than %.

Ethylene glycol can penetrate the body through the skin and through inhalation. Therefore, it is very dangerous to use ethylene glycol coolant in open systems– fumes will spread indoors; V double-circuit boilers Poisonous coolant may be mixed into hot water.

With prolonged exposure, chronic poisoning with damage to vital organs/vessels is possible; kidneys; nervous system/.

The first signs of poisoning are depressed mood and lethargy.

It is especially worth remembering that ethylene glycol does not have an unpleasant odor and has a sweetish taste, which poses an increased danger to children and animals in the event of coolant leaks from the system.

When water completely evaporates from the antifreeze composition during subsequent cooling, ethylene glycol freezes at a temperature of minus – °C.

Has high viscosity at low temperatures.

Spent coolant based on ethylene glycol must not be poured into open ground or into sewers; it must be collected and sent for recycling.

In the event of a spill in a residential building, floor boards, tiles, and insulation impregnated with ethylene glycol coolant must be replaced.

Ethylene glycol-based coolants are safe to use in closed heating systems, with a closed expansion tank, for heating non-residential premises.
For security purposes, constant monitoring of the system is required.

Coolant-antifreeze, or antifreeze for cars?

Functionally, it can be used in heat exchange systems: automotive antifreeze, which was often practiced in Russia due to the insufficient availability of household coolants-antifreeze. The use of automotive fluids /antifreeze or antifreeze/ in systems is possible if they are manufactured using technology that involves the use of fluid for cooling internal combustion engines, as well as as a working fluid in heat exchangers operating at low and moderate temperatures.

Conventional additive packages – automobile antifreeze And antifreeze are not designed for long-term and intensive use in domestic heating systems. In some cases, additives contained in modern auto fluids and designed for automotive engine alloys may not be compatible with heating system materials.

It should also be remembered that - automotive antifreeze all inherent environmental disadvantages coolants based on – ethylene glycol.

In addition, automotive antifreeze additives often include - toxic substances, which may pose a danger to – person And animals.

COOLANT BASED ON PROPYLENE GLYCOL

Advantages Flaws
  • It certainly insures the system against rupture. The physical state when not in use at low temperatures is liquid /mushy/. When freezing, the volume increases by only -% /ethylene glycol coolant - approximately -%/. There is no need to drain the system in winter;
  • Unlike water, a water-glycol solution and, accordingly, a coolant freezes gradually: during the cooling process, crystals begin to form in the liquid. Then, with further cooling of the liquid, there are more and more crystals in it (so-called slush is formed), and, finally, at a certain lower final temperature, this sludge solidifies.
    Propylene-glycol coolant is practically the only product of this purpose when, with complete evaporation of water from the coolant composition during subsequent cooling, propylene glycol does not freeze to minus - °C / ethylene glycol, we recall, freezes at - °C/;
  • Environmentally and toxicologically safe. Provides the highest level of safety after water. Its performance is several times higher than that of ethylene glycol coolant. Toxicity of ethylene glycol LD 50 – 4 700 mg/kg.
  • Toxicity of propylene glycol LD – 20 300 23 900 mg/kg. It is not dangerous even after prolonged inhalation of vapors and does not cause poisoning if accidentally ingested;
  • Non-corrosive. Compatible with all structural materials of systems;
  • Good thermophysical properties.
    Despite its viscosity, the coolant based on propylene glycol has a lubricating effect, reducing hydrodynamic resistance and improving the operating conditions of pumps in the secondary circuit;
  • Does not form scale;
  • Propylene glycol helps remove internal surfaces heat exchange equipment for deposits;
  • Coolant based on propylene glycol has a lower density compared to ethylene glycol coolants and due to this, less energy is consumed for pumping the coolant;
  • Fire and explosion proof;
  • Little volatile.
  • In case of a spill, there is no need to replace the floor, tiles, or insulation; it is enough to remove the coolant and rinse the surface with water.
Higher cost than other types of coolants. The initial cost of propylene glycol-based coolant is only apparent. She makes excuses minimal costs for system repairs, low operating costs and labor costs, ensuring safety, and no costs for connecting to centralized heating systems.

It should also be borne in mind that the cost of high-quality coolant is preferable to the cost of repairing expensive equipment.

Coolant /antifreeze/ “Comfort” brand “ A", produced by PA "Khimprom" Kemerovo, due to the manufacture based on our own raw materials - the cheapest in Russia!

It can be used in systems that have heating elements outside the building or in the attic.

The wrong choice of antifreeze and non-compliance with operating rules can cause many problems during operation, up to complete failure of the system.

Heating and water supply is a multifaceted engineering process,

requiring the knowledge and skills of a PROFESSIONAL.

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Plumbing work Tyumen

A glycerin-based coolant is a solution of glycerin in water with the addition of various additives and dye.

The presence of glycerin in the coolant reduces its freezing point, which makes the heating system (CO) more resistant to malfunctions that lead to temporary cessation of operation of the heating boiler.

The probability that the glycerin-based coolant will freeze in the lines, which will lead to their rupture and failure of the CO, is significantly less than that which exists for systems using only water as a coolant.

Glycerin in the heating system is the main factor influencing the further choice of the CO project for a private house, the type of heating boiler, the power of the installed heating devices(convectors or radiators), on the power of the main pump and the list of materials used.

Technical characteristics of glycerin coolants

Glycerin based coolant

When deciding to purchase a coolant produced using glycerin, you should definitely analyze the main parameters of the latter so as not to experience unnecessary difficulties in the future with the operation and maintenance of CO:

  • The temperature range in which the specified coolant will operate normally, without significant losses in its consumer parameters.
  • The heat capacity of glycerin, i.e. the required amount of coolant that needs to be pumped per unit of time in order to transfer the required amount of heat.
  • Viscosity coefficient, which affects the circulation rate of the coolant, the value of the heat transfer coefficient, etc. and its change depending on the temperature of the coolant.
  • Corrosive activity, which imposes a number of restrictions on the use of coolant with glycerin additives without adding the required corrosion inhibitors, as well as on the choice of coolant circuit material.
  • Safety issues regarding the use of such coolants for environment and man.
  • Lubricity, which determines the restrictions imposed by the use of the specified coolant on the design of CO elements.
  • An indicator of inertness to foaming, which directly affects the efficiency of the transfer pump.

The ideal choice is a glycerin-based coolant, the chemical composition of which takes into account the possible results of its interaction with all substances currently used in the designs of heating boilers and CO heating lines of private houses (steel, cast iron, copper, aluminum).
Because otherwise reactions may occur leading to electrochemical corrosion.

Glycerin in the heating system must have additives that prevent oxidation and foaming.

Benefits of using glycerin for heating

  1. A coolant containing glycerin has a significantly lower crystallization temperature (the freezing point of glycerin is minus 30 degrees).
  2. Glycerin is explosion- and fire-safe because it doesn't ignite at all.
  3. Such coolants are harmless to health.
  4. The level of heat transfer significantly exceeds similar indicators of other coolants.
  5. CO with the specified coolant is capable of operating at temperatures from -30 degrees to +105 degrees.

Glycerin for heating does not have a hazard class assigned to it and, according to international standards, is considered a food additive with code E 422.

Disadvantages of glycerin-based coolants

  1. The high viscosity of the coolant requires pumps of increased power and performance, or dilution with various alcohols, including methyl alcohol.
  2. Strong foaming, leading to the appearance of air in the heating lines, which impairs the heat transfer of the network.
  3. The presence of glycerin sharply increases the quality requirements for seals and gaskets used in CO, which are made of plastic and non-polar rubber.
  4. The likelihood of corrosion in the metal parts of the CO increases significantly.
  5. High-temperature heating of glycerin leads to the formation of acrolein, which is a highly toxic substance with extremely unpleasant smell and tear effect.

Having given preference to non-freezing liquid, you need to understand that the system does not require car antifreeze, ethanol or transformer oil, but a special glycerin-based antifreeze, which is created specifically for use in heating systems.

We cannot discount the requirements regarding fire safety, as well as the requirements for the chemical composition of antifreeze from the point of view of the safety of its components for human health.

The use of glycerin in heating systems

Any manipulations with coolant containing glycerin for heating, such as filling or replacement, require professional training and special equipment.
Therefore, they must be performed by specialists.

It is recommended to store coolants made using glycerin in a hermetically sealed container specially designed for this purpose and in a cold room.

It is necessary to protect this coolant from direct sunlight, as this can lead to chemical reaction decomposition of additives included in the coolant and the main substance.

In all other cases, the specified coolant is stable and retains its properties without changes for eight years.

The best coolant in composition is ordinary water. It is worth diluting water with antifreeze and pouring it into the heating system only if absolutely necessary. Numerous negative aspects of antifreeze greatly prevail over positive qualities water coolant.

When making your final decision, weigh the performance efficiency of water and antifreeze-based coolant. We have been convinced many times that water as a coolant is the optimal solution. Any antifreeze included in the coolant should be used only in one case, which we will talk about in detail today.

The efficiency of heating your home largely depends on what coolant you use in the heating system country house. The coolant is the final touch that will help sparkle with all the colors of your heating system, bringing coziness and comfort to your home. Despite the apparent simplicity of choosing a coolant, you should approach this process as carefully and responsibly as possible.

Coolant that accumulates and transfers thermal energy, inevitably passes through the heart of the heating system, which is an expensive boiler. In addition, the coolant washes the pump rotor, cooling the engine in forced system heating. And of course, the coolant directly affects pipes, fittings and radiators. Avoiding harmful effects on all elements of the system and ensuring maximum heat transfer coefficient is the main task that the owner needs to solve when choosing a coolant for the heating system of a country house.

Coolant - basic requirements in a heating system

What should be the coolant for the system? autonomous heating? Let's try to formulate the necessary criteria for compliance with the “ideal” option.

  • Let's start with the fact that we will need a heating fluid with the highest possible heat capacity. This condition is necessary for high-quality accumulation and further release of thermal energy through radiators.
  • We will need a coolant with a chemical composition that does not activate corrosion processes in boiler equipment, pipe distribution, heating and radiator, shut-off and control and other heating system structures.
  • Special requirements should be placed on the chemical component of the coolant. The compound passes through the seals pumping equipment, and others structural elements containing rubber O-rings and may expose them to destruction.
  • One of the main indicators indicating that you have a high-quality coolant at your disposal is wide range temperature use. A manufacturer that cares about its reputation offers a coolant with performance characteristics ranging from low crystallization temperature values ​​to high boiling threshold values.
  • The coolant should not contain salt, which “loves” to fall out in the form of scale in the heat exchanger, rendering it inoperable, and also to grow as solid deposits in the internal section of the pipes.
  • It is necessary that the heating fluid has increased stability. We will need a coolant that does not disintegrate into its component parts over time, either under the influence of high temperatures or under the influence of its chemical composition. Throughout its service life, the coolant must maintain the declared technical characteristics, such as: density, fluidity, heat capacity, chemical inertness.
  • In addition, the coolant should not threaten the health of residents in the event of leaks. Toxic fumes are not allowed. The liquid used for heating must be completely non-flammable and not form explosive gas mixtures upon evaporation.
  • As a rule, the heating system has significant volumes, so one of the important criteria for a thrifty homeowner is the acceptable cost of the coolant.

Coolant: Glycol or Water?

On the one hand, almost all the necessary requirements are met by the simplest liquid for heating systems - water. Water is not dangerous, does not harm the environment, has a high heat capacity coefficient, and the operating periods are not regulated by a time interval.

However, one significant disadvantage negates all the advantages - water crystallizes already at zero temperature. Quite often, we do not heat our home for the full duration of the heating season. Often we leave country houses during vacation or simply go to the city. In this case, during downtime, water will do a disservice. When freezing, we will most likely encounter failure of the boiler, pipes and radiators.

In such cases, liquids containing propylene glycol or other antifreezes come to the rescue. Being exposed negative temperatures, such liquids largely lose their fluidity, but do not freeze and do not have a sharp expansion coefficient, as a result of which the equipment remains in working order, even when subjected to freezing.

Water

Thus, it is not difficult to decide which coolant to use for the heating system: for constant operation and maintaining a positive temperature, we recommend using ordinary pre-settled and boiled water. Ordinary tap water contains various salts and is saturated with oxygen, which contribute to the deposition of scale in the heating system.

Boiled water will reduce the occurrence of scale in the heat exchanger, since during boiling the percentage of dissolved gases O2, Cl, H2S decreases and the water softens slightly. The disadvantage of this method is that it is difficult to carry out the task of boiling large volumes of water. In addition, boiling does not provide complete removal of dissolved salts.

The most effective is the use of so-called “softener filters.” Such filters carry out cleaning based on the reagent, ion exchange or electromagnetic principle of influence. You can purchase such a product in special stores. thermal equipment. Most of these filters are used specifically for boiler water preparation. In addition, you can filter the water yourself using an ion exchange filter (GEYSER type).

There is a practice of mixing special reagents with water to help soften it. A well-known remedy is soda ash; sodium orthophosphate is also used. In both cases, you need to be moderate and follow the indicated dosage. Exceeding the ratios leads to the opposite effect; such a coolant has reduced thermal characteristics and provokes the corrosiveness of the solution.

The best option, however, would be to purchase water from a company engaged in production drinking water. The most expensive solution is to use distilled liquid.

Antifreeze

If you use your home as a temporary residence or often leave it in winter, then the only the right decision the heating system will be operated with a coolant containing glycol or glycerin. Such liquids will allow you to leave the heating circuit and boiler equipment unattended for a long time. The use of antifreeze virtually eliminates the possibility of heating equipment “defrosting”. In addition, you don’t have to worry about scale deposits.

We invite you to get acquainted with well-known manufacturers, and also understand the three main compositions used in coolants. Consider their distinctive characteristics and areas of application. Today, the domestic market does not experience a shortage of antifreeze mixtures. Antifreeze for heating a country house or summer cottage can be found at any construction market.

Coolant for heating system

Modern coolant has a complex set of components chemical elements. Known antifreeze fluids used in heating systems are based on three fundamental components. Accordingly, each liquid is endowed with different properties and characteristics. The main difference in the technical characteristics of the presented brands is determined by the fillers on which the coolant is mixed:

- ethylene glycol;

- propylene glycol;- glycerin.

The coolant is produced in the form of a concentrate or is often offered a little more expensive, ready for use, without additional enrichment with water. Manufacturers offer high-quality antifreeze. Thanks to the moderate concentration and proper proportions of polyhydric alcohol, a good coolant does not “corrode” the rubber gaskets of pumping equipment. There is a complete absence of negative impact on polypropylene or metal-plastic pipes.

The Russian market offers antifreeze liquids with a huge variety of brands from various, both domestic and foreign manufacturers. In common parlance, “anti-freeze” is found under the names: “Warm House”, “Dixis”, “Thermagent Eco”, “Thermos Eco”, “TeploDom”, “Antifrogen N” and many others. As a rule, antifreezes have different colors, repeating almost the entire range of the rainbow palette: green, blue, yellow, red and even pink.

Ethylene glycol based coolant

Most likely, due to its simple preparation and low cost, the group of antifreezes that contain ethylene glycol is the most common among others. As we noted, the coolant is found in the form of a concentrate or in a ready-made solution, usually with a crystallization threshold at -30º C. Antifreeze is red, supplied in cans from 10 to 50 liters. The declared characteristics in a concentrated state are capable of serving a temperature range from – 65º to + 110º C.

If necessary, guided by climatic realities, you can always bring the coolant to the required crystallization value. The requirement for antifreeze concentration is regulated service center Your boiler and pumping equipment. It is recommended to mix the concentrate with distilled water according to the table below. The red color of antifreeze warns of the need to adhere to the strictest safety measures.

Water percentage

Concentrate percentage

Freezing threshold

Boiling threshold

Disadvantages of Ethylene Glycol

  • Ethylene glycol foams when exposed to high temperatures, forming air pockets in the system. Manufacturers solve the problem by adding special additives. Additives help to avoid foam formation, including preventing corrosion processes in metal elements designs. Galvanized elements should be avoided - they are susceptible to negative impact ethylene glycol, despite additives.
  • The negative point is the irreversible process of decomposition of ethylene glycol when the boiling point is reached. During the degradation of antifreeze, a hard, insoluble precipitate is formed, which settles in the pipeline or heat exchanger. The liquid residue takes on the character of aggressive acids that promote corrosion processes. Additives lose their positive properties and no longer prevent foaming of the coolant.

Thus, ethylene glycol antifreeze can be used only when boiler equipment is equipped with a control and adjustment system that maintains specified temperatures.

  • Ethylene glycol is a highly toxic product. Penetration of a substance into a heated living space (liquid or vapor phase) seriously threatens the health of residents. Contact of ethylene glycol-based coolant on exposed skin is unacceptable. That is why the use of ethylene glycol antifreeze is allowed only in “closed” heating systems, with a closed expansion tank equipped with a membrane. The use of ethylene glycol in a double-circuit boiler is not allowed.

As we can see, there are a lot of shortcomings, and quite significant ones at that. The only attractive aspect is the low cost of the product. The price of ready-made formulations does not exceed 60 rubles per liter, the cost of concentrated products stops at 90 rubles per liter in 2017 prices.

A significant limitation to the use of ethylene glycol as a coolant is the manufacturers of wall-mounted gas boiler equipment. Companies strictly prohibit the injection of ethylene glycol-based antifreeze into systems using their devices and withdraw them from warranty service if the rules are ignored by the consumer.

Propylene glycol based coolant

Propylene glycol defines the concept as environmentally friendly pure product and the logo “ ECO", which by the way, is highlighted for good reason. In heat exchange equipment in the temperature range from −40 °C to +108 °C, propylene glycol and antifreezes based on it are absolutely non-toxic.

Unlike ethylene glycol, propylene glycol coolant is approved for use in double-circuit boilers. The characteristics of the composition allow mixing a small amount with hot water, without serious consequences for the skin or digestive tract.

Propylene glycol - pros

  • Environmental friendliness. Some types of propylene glycol serve as raw materials in the production process of the food industry, such as various containers and packaging containers.
  • The heat capacity is higher compared to ethylene glycol.
  • Safety in work related to filling the heating system.
  • Lubrication effect. There is a significant decrease in the hydraulic resistance coefficients in the circuit. This increases the efficiency of heating systems and reduces energy losses.

Propylene glycol - cons

  • Incompatibility of operation with zinc-coated elements.
  • Due to its environmental friendliness and good performance characteristics, the cost of coolants based on propylene glycol is approximately 40-50% higher than ethylene glycol. The price starts from 100 rubles per liter. Manufacturers add various additives that improve the characteristics and increase the service life (up to 10 years) of the coolant; the price of such brands can reach 300 rubles per liter.
  • Lack of concentrated product. Mostly on the shelves you can find the coolant in diluted compositions at a certain crystallization temperature.

The next type of coolant that we will consider is based on a solution with glycerin. We are often asked which coolant glycerin or propylene glycol should be chosen for the most efficient operation of the heating system, let's figure it out.

Coolant – glycerin

Glycerin has been used as antifreeze compounds since the end of the last century. The characteristics and properties are more like a cross between ethylene glycol and propylene glycol. The price range is also located in the middle with a bias towards expensive coolant.

Opinions regarding the advisability of using glycerin in heating systems are often diametrically opposed. We will try to compose SWOT analysis based on the arguments of supporters and opponents, since the truth is somewhere in the middle of the judgments.

Glycerin - advantages

  • Glycerin is a colorless liquid, can be mixed with water in any ratio, and is absolutely safe for humans and the environment.
  • Has wide performance characteristics. The lower limit of the beginning of crystallization is at the point - 30 ºС. The beginning of the boiling stage is comparable to water, or slightly above +110 ºС.
  • No expansion when freezing. When thawing, the properties and characteristics are restored in full.
  • Does not react with zinc coating.
  • Does not damage sealing rings and materials, does not cause leaks in connecting elements.
  • Meets fire safety requirements. Not flammable. Explosion-safe.
  • Glycerin coolant does not require flushing the system after using other solutions in it previously.
  • Durability. The warranty periods stated by the manufacturers range from 7 to 10 years.
  • The technical characteristics are almost identical to propylene glycol, while the price of glycerin coolant is 25% more affordable.

Glycerin - cons

It is worth noting that glycerin in antifreeze is known and used at the beginning of the 20th century, at the dawn of heating systems. Subsequently, they were replaced by cheaper analogues of glycol coolants. Thus, glycerin antifreeze is not an innovation, but rather a new look at a forgotten past.

  • Glycerin has high density and viscosity. It is necessary to increase the rotation speed of the pump in order to increase the flow, which further loads the heating equipment.
  • The heat capacity values ​​are lower than those of water and are inferior to propylene glycol.
  • The heat resistance of glycerin leaves much to be desired; foaming of the product can be observed even at temperatures of about 90ºC. Of course, the problem is solved by adding additives, but the price also increases.
  • Elevated temperature conditions lead to the chemical breakdown of glycerol. The resulting solid sediment settles on the walls of the system and is difficult to clean.
  • A highly volatile lachrymal liquid with a pungent odor, released during decomposition, is acrolein, which is equated to carcinogenic substances.
  • Evaporating water from the solution causes glycerin to thicken and lose its positive properties. The next step is the formation of a jelly-like substance, already at a temperature of +15 ºС. As a result, the coolant completely loses its performance characteristics, followed by replacement with a new one.
  • The production process is not regulated by GOST. There are only technical specifications(TU), which unscrupulous manufacturers interpret based on their capabilities. Sometimes there are simply no guarantees. It is not surprising that it is glycerin that most often acts as a counterfeit product, especially since it is cheaper than propylene glycol.

To summarize, it remains to add that in European countries that are members of the EU, the production and use of coolant based on ethylene glycol is prohibited by law. At the same time, there is no development of glycerin-containing products, since this approach is unpromising and ineffective. With this review, if you have a coolant based on glycerin or propylene glycol on hand, it is better to opt for the latter.

How to choose the right coolant for a heating system

How to select a coolant for a heating system and choose a suitable antifreeze is not an idle question. Of course, it is better to use water, but if you expect heating downtime, you will need antifreeze. It should be taken into account that different compositions have distinctive characteristics of thermal conductivity and heat capacity.

Add to this the fact that antifreeze will require up to 10% additional capacity of your system when compared to plain water. Despite the fact that the crystallization threshold is lower, the coefficient of thermal expansion of non-freezing liquid is slightly higher compared to water.

Taking into account the set of coolant parameters, it is selected suitable equipment for heating your home. As an example, the size of the expansion tank is selected based on compliance with the parameters specified in the table. There is a dependence on the volume of coolant pumped into the heating system.

When choosing an antifreeze liquid, the most important consideration should be given to the type of your heating system: open or closed. The actual parameters of the coolant will also depend on the design of the boiler. Wall-mounted installation will require a more “gentle” approach as opposed to floor-mounted installation.

Some of the antifreezes discussed above are not permissible for use in dual-circuit versions and are suitable only for single-circuit versions. Taken together, all this affects both the cost, heating efficiency, and ultimately your healthy well-being.

How to pour coolant into the heating system

The easiest way to pour coolant into a finished heating system is to gradually fill the expansion tank until it is completely filled. Of course, this simple method is only suitable for open-type structures. The manual filling method will not require you to additional equipment- maybe a bucket and a ladle.

The procedure for pumping coolant into a closed system circuit is a little more complicated. It will be necessary to install an additional “tie-in” into the pipeline circuit. It’s good if the mechanics and installers prudently do this work in advance, during the installation work. You can install a standard tee with a threaded connection of no more than half an inch. Next, using a threaded connection, screw on a shut-off valve equipped with a fitting for connecting hoses using a clamp.

Coolant must be pumped under pressure. A hand pump is suitable to create pressure. You can also use inexpensive electric submersible pump type “Baby”. To make the process more efficient, pour all the required coolant into one large container. After filling the system, be sure to return the valve to its original closed position.

We advise you to pay attention to the boiler operating instructions; perhaps your modern unit already has a built-in make-up tap on its body. In this case, it will be easier for you to fill and subsequently add antifreeze directly through the boiler equipment.

We hope our article helped you find the answer to which coolant for a country house heating system is best suited to your needs. By choosing an antifreeze based on propylene glycol, ethylene glycol or glycerin, you can be sure that this is the optimal solution for domestic conditions, in the absence of year-round heating.

Moreover, high-quality antifreeze additives will help prolong the life of the equipment and protect your circuit from corrosive processes and the formation of scale deposits.

The main condition that you must strictly observe in order to choose the right coolant is to follow the manufacturer’s recommendations and carefully read the boiler instructions. Often the manufacturer gives advice, including the recommended brand and composition of the ratio of the proportions of antifreeze liquid and water. Also, keep in mind that the coolant does not retain its beneficial properties forever and must be replaced approximately once every 5-7 years.

A glycerin-based coolant is a solution of glycerin in water with the addition of various additives and dye.

The presence of glycerin in the coolant reduces its freezing point, which makes the heating system (CO) more resistant to malfunctions that lead to temporary cessation of operation of the heating boiler.

The probability that the glycerin-based coolant will freeze in the lines, which will lead to their rupture and failure of the CO, is significantly less than that which exists for systems using only water as a coolant.

Glycerin in the heating system is the main factor influencing the further choice of the CO project for a private house, the type of heating boiler, the power of installed heating devices (convectors or radiators), the power of the main pump and the list of materials used.

Technical characteristics of glycerin coolants

When deciding to purchase a coolant produced using glycerin, you should definitely analyze the main parameters of the latter so as not to experience unnecessary difficulties in the future with the operation and maintenance of CO:

  • The temperature range in which the specified coolant will operate normally, without significant losses in its consumer parameters.
  • The heat capacity of glycerin, i.e. the required amount of coolant that needs to be pumped per unit of time in order to transfer the required amount of heat.
  • Viscosity coefficient, which affects the circulation rate of the coolant, the value of the heat transfer coefficient, etc. and its change depending on the temperature of the coolant.
  • Corrosive activity, which imposes a number of restrictions on the use of coolant with glycerin additives without adding the required corrosion inhibitors, as well as on the choice of coolant circuit material.
  • Issues of safety of using such coolants for the environment and humans.
  • Lubricity, which determines the restrictions imposed by the use of the specified coolant on the design of CO elements.
  • An indicator of inertness to foaming, which directly affects the efficiency of the transfer pump.

The ideal choice is a glycerin-based coolant, the chemical composition of which takes into account the possible results of its interaction with all substances currently used in the designs of heating boilers and CO heating lines of private houses (steel, cast iron, copper, aluminum).
Because otherwise reactions may occur leading to electrochemical corrosion.

Glycerin in the heating system must have additives that prevent oxidation and foaming.

Benefits of using glycerin for heating

  1. A coolant containing glycerin has a significantly lower crystallization temperature (the freezing point of glycerin is minus 30 degrees).
  2. Glycerin is explosion- and fire-safe because it doesn't ignite at all.
  3. Such coolants are harmless to health.
  4. The level of heat transfer significantly exceeds similar indicators of other coolants.
  5. CO with the specified coolant is capable of operating at temperatures from -30 degrees to +105 degrees.

Glycerin for heating does not have a hazard class assigned to it and, according to international standards, is considered a food additive with code E 422.

Disadvantages of glycerin-based coolants

  1. The high viscosity of the coolant requires pumps of increased power and performance, or dilution with various alcohols, including methyl alcohol.
  2. Strong foaming, leading to the appearance of air in the heating lines, which impairs the heat transfer of the network.
  3. The presence of glycerin sharply increases the quality requirements for seals and gaskets used in CO, which are made of plastic and non-polar rubber.
  4. The likelihood of corrosion in the metal parts of the CO increases significantly.
  5. High-temperature heating of glycerin leads to the formation of acrolein, which is a highly toxic substance with an extremely unpleasant odor and tear-producing effect.

Having given preference to a non-freezing liquid, you need to understand that the system does not require car antifreeze, ethyl alcohol or transformer oil, but a special glycerin-based antifreeze, which is created specifically for use in heating systems.

We cannot discount the requirements regarding fire safety, as well as the requirements for the chemical composition of antifreeze from the point of view of the safety of its components for human health.

The use of glycerin in heating systems

Any manipulations with coolant containing glycerin for heating, such as filling or replacement, require professional training and special equipment.
Therefore, they must be performed by specialists.

It is recommended to store coolants made using glycerin in a hermetically sealed container specially designed for this purpose and in a cold room.

It is necessary to protect this coolant from direct sunlight, as this can lead to a chemical reaction of decomposition of the additives included in the coolant and the main substance.

In all other cases, the specified coolant is stable and retains its properties without changes for eight years.

Article rating:

22.11.13 Source: http://teplo-faq.net/

As is known, both water and non-freezing liquids - antifreezes - can be used as a coolant in heating systems. Each of these coolants has its own advantages and disadvantages. We will tell you about them today.

Water, with its ability to accumulate large amounts of heat when heated and release large amounts of heat when cooled, is an excellent coolant. It has good fluidity and therefore easily circulates through the heating system. In addition, water is always at hand, and if you need to add it to the heating system, there are no problems. It is also important that we are talking about an environmentally friendly substance. Consequently, a possible leak will not cause an “ecological disaster” on the scale of a single house. But! All these advantages are offset by one significant drawback - the possibility of freezing of water in the system and, as a result, putting it out of action (you cannot leave a house with the heating system turned off but full in winter). Another disadvantage is the need to change the chemical composition of water before using it for heating. In addition, no matter how you prepare it, corrosion still occurs on all metal parts of the heating system.

The use of water as a coolant, in addition to its main advantage - low price, poses the following problems:
metal corrosion under the influence of coolant;
scale formation on the walls of equipment;
change in the composition of the coolant during operation and, accordingly, its thermophysical properties
Due to freezing, pipelines and heating elements rupture

These problems, if not paid due attention to them, lead to a reduction in the service life of heating equipment, increased costs for carrying out preventive and repair work, requiring in some cases to stop it, which, in turn, can cause deterioration in quality or damage to the coolant.

Coolants based on saline solutions are very economical in terms of direct costs. However, due to the high aggressiveness of these solutions, indirect costs associated with equipment failure exceed direct costs several times. Therefore, there is a tendency to replace them with coolants that provide greater reliability of heating equipment. These primarily include aqueous solutions of polyhydric alcohols, including propylene glycol (PG), ethylene glycol, and glycerin.

The undoubted advantages of glycol-based coolants include “non-freezing” at sub-zero temperatures. It’s not that they don’t freeze at all, it’s just that this doesn’t happen to them in the usual (everyday) sense. Unlike water, they form not a crystalline, but, so to speak, an amorphous structure. At the same time, the coolant does not increase the volume, and, therefore, does not destroy (does not “defrost”) the heating system. When the temperature rises, it again turns into a liquid state and can perform its functions. It is this property that makes glycol-based coolants almost irreplaceable - if they don’t live in the house in winter, it is not necessary to drain the heating system. And that means there is an opportunity to quickly heat the rooms when you arrive on the weekend.

Brief characteristics of glycols

Glycols are colorless, sweetish and highly viscous liquids with a freezing point below -50C. There are three main types of glycols:

- ethylene glycol - C2H4(OH)2. It is a toxic substance (GOST 19710-83), and is mainly used where its leakage will not be dangerous to people, animals and food products.

Coolant "Gulfstream-65" is produced on the basis of high-quality monoethylene glycol with the use of a balanced package of functional additives (anti-corrosion, anti-foam, antioxidant and heat-stabilizing, as well as additives that increase inertness to sealing materials), providing protection of the heating system from foaming, scale and corrosion.

- propylene glycol - C3H6 (OH)2. They compare favorably in toxicological properties with traditional coolants technical purpose based on ethylene glycol. Due to its non-toxic properties, it is also used in the food industry (as food additives).

The safe coolant "THERMAGENT EKO -30" is produced on the basis of pharmacological propylene glycol DOW (Germany) and using the latest technology "Organic Acid technology". Contains non-toxic, organic (carboxylate) corrosion inhibitors and a package of special additives made in Germany.

- glycerin – C3H5(OH)3 When aqueous solutions of glycerin are used as coolants, the requirements for gaskets (seals) and equipment parts made of non-polar rubbers and plastics of some brands are increased. At temperatures below -20 °C glycerin solutions have large values viscosity than solutions prepared on the basis of ethylene and propylene glycols, which causes special cases installation additional pump for coolant circulation. In addition, corrosion problems are more difficult to solve. In the high-temperature (burner) heating zone of a glycerin-based coolant, the formation of an unsaturated aldehyde - acrolein, (CH2=CH-CH+O), a substance with a strong unpleasant odor, is possible.

The coolant "Antifreeze EKO-30" is used in autonomous heating systems. The coolant is based on glycerin, which is completely safe for humans. EKO-30 antifreeze includes a set of anti-foam and anti-corrosion additives, thanks to which it ensures high-quality, efficient and safe operation of heating systems. Features of the use of glycol solutions.

Aqueous solutions of ethylene glycol and propylene glycol have thermophysical properties different from water - heat capacity, density, thermal conductivity, chemical activity, etc., which must be taken into account when selecting equipment and hydraulic calculations of refrigeration systems.

Both propylene glycol and ethylene glycol have a flow rate higher than that of water. This property can lead to the formation of leaks in seals (especially at low coolant temperatures and high glycol concentrations) and requires a more careful approach to the selection of pumping equipment and its placement. In some cases, standard pumps are designed for a maximum glycol content of 30-40%; higher concentrations require replacing standard seals with special ones. If possible, pumps should be located in parts of the system with higher coolant temperatures.
It is not recommended to use galvanized steel pipes in systems with glycol coolants.

Helpful Tips:

Before pouring coolant into the old system, it is necessary to first rinse it with a surface cleaning liquid. To more quickly remove air bubbles from household antifreeze, it is recommended that after filling the system, keep it without pressure for 2-3 hours.

What liquids should be used in the heating system? Car antifreeze is not suitable here, since it is made on the basis of ethylene glycol. Although salt solutions freeze at temperatures lower than water, they are also not suitable, since they are highly corrosive. You should use so-called “household antifreezes” - coolants specifically designed for heating systems. What are these substances and how are they characterized?

Coolants based on ethylene glycol could be used everywhere. But... Ethylene glycol, which is part of antifreeze, becomes a “poison” when it enters the human body (belongs to the third danger group) - a one-time “take” of just 100 ml of this substance can become a lethal dose for an adult. That is why antifreezes on this basis are recommended for use exclusively (!) in closed heating systems (with a closed expansion tank). And you shouldn’t fall for the assurances of some “experts” that an open tank in a ventilated attic does not pose any danger.

But what if the system is open (an open expansion tank is used)? Exactly such country houses, cottages and residential buildings are the vast majority. For them, the solution is to use antifreezes not based on ethylene glycol, but on the basis of propylene glycol, which, with almost the same properties, are absolutely non-toxic (since 1996, in the USA, Germany, France and some other countries, the transition to propylene glycol antifreezes, so-called eco-friendly, began - antifreeze).

Features of the use of antifreeze in heating systems.

When using domestic cast iron radiators antifreeze must be used extremely carefully - unfortunately, radiators often have the wrong rubber installed technical documentation. Some would-be manufacturers use hoses to make gaskets, the rubber of which is eaten away by antifreeze extremely quickly.

Many manufacturers claim that it is not ethylene glycol that evaporates from antifreeze, but only water, and therefore these antifreezes are practically not dangerous. This statement is unsubstantiated and controversial, since the boiling point of ethylene glycol is only twice as high as that of water. But, be that as it may, if ethylene glycol antifreeze is already poured into the system, its evaporation from the open expansion tank should be minimized by installing a wooden float in it that covers the entire surface. This is exactly what foreign manufacturers of antifreeze advise to do, despite the claim of harmlessness.

In heating systems with antifreeze, not all membrane expansion tanks can be used - not all rubber used in them will withstand “communication” with such a coolant. Therefore, when choosing an expansion tank, you need to make sure that it is designed to work with antifreeze.

In our research, we encountered the fact that when diluting the concentrate of some antifreezes, the “local” water used for this can give a reaction accompanied by precipitation. This sediment mainly contains additives that are so necessary for antifreeze. To insure against this phenomenon, it makes sense to either purchase ready-to-use antifreeze that does not require dilution, or use distilled water for dilution.

Some thermostats, widely used in heating systems, have two setting scales: “working” (this is what the consumer sees and uses) and “installation” (hidden inside the thermostat and accessible only to installers). The “mounting” scale regulates the opening of the diaphragm for the passage of coolant, and if it is installed at a position with minimal opening (positions 1 or 2 out of 7-8 available), then a rather narrow opening is obtained, followed by a sharp expansion. The passage of coolant through such a diaphragm leads to air separation and, as a consequence, to the formation of an air lock or foaming. For water this phenomenon is simply unpleasant, but for antifreeze it is completely unacceptable. Therefore, if antifreeze is used in the heating system, the “installation” setting should include installation to position at least 3 (and, if possible, higher). And this setting must be monitored at the stage of installing thermostats.

No matter how good automatic air vents are, it is better to use them in heating systems with antifreeze. hand tools. This is due to the possibility of antifreeze foaming. This provision has not yet been enshrined in official recommendations, but operational practice has already fully confirmed it.

When installing heating systems with steel pipes for sealing threaded connections Flax tow should absolutely not be used in combination with paint. Unlike water, antifreeze does not cause flax to swell. He simply “eats” the paint. For installation, it is better to use special sealants, for example from LOCTITE (HENKEL concern): Loctite-55 - ready-to-use, uncured sealing fiber made from complex threads, wound onto the turns of pipeline threads directly from a compact container, which is equipped with a built-in knife, Loctite-542 - single-component threaded sealants, the polymerization of which forms a rigid insoluble plastic mass that fills the threaded gap. Similar sealants are available from other companies. Of course, these products are not very cheap, but their use is fully justified by the reliability of installation.

Before pouring antifreeze into the system, it must be washed with special compounds. The “kits” produced for such treatment include 2 components - a rinsing agent (acid composition) and a substance that neutralizes the effect of the rinsing acid. The operation must be carried out before the first pouring of antifreeze into the system, especially after using water as a coolant. Otherwise, there is a risk that the antifreeze will “eat away” the rust and scale, and the fallen deposits will simply clog the pipes of the heating system.

Due to the evaporation of antifreeze in open systems, there is often a need to top it up. If you have antifreeze in stock that was previously poured into the system, then there will be no problems. If there is no stock, it is worth purchasing and using exactly the antifreeze that was used previously. A “new” coolant can be added only if you are completely sure that it is absolutely compatible with the “old” one - if they are incompatible, it is possible that some (or even all) of the additives present in antifreeze will precipitate. The consequences of removing additives from the composition may be unpredictable. Therefore, if you are not sure of the complete compatibility of the components, it is better to simply add distilled water to the system or completely drain the “old” antifreeze, flush the system and only then use the “new” one.

All three of the above substances belong to the so-called. polyhydric alcohols - substances that have two or more -OH groups in their molecules, due to which many hydrogen bonds are formed between their molecules, and the substances themselves are easily mixed with water in any ratio. From the point of view of their effects on the body, glycerin solutions are completely harmless, since it is naturally found in dietary fats and is registered as a food additive E422. Propylene glycol is not included in food, but in most countries it is registered as a food additive E1520 and is often used in shampoos, cosmetics, pharmaceutical products, etc. Finally, ethylene glycol is a moderately toxic substance: its LD50 is approximately 4700 mg/kg (for comparison, the LD50 of table salt is about 3000 mg/kg - i.e., when taken orally, it is formally much more dangerous).

What to choose - a coolant based on glycerin, propylene glycol or ethylene glycol?

From a technical point of view, an antifreeze additive to the coolant must meet a whole set of requirements, the most important of which are:

  • the amount of antifreeze that needs to be introduced into the solution to lower its freezing point by the required amount;
  • own chemical and corrosive inertness of the additive to the environment (pipes, pumps, fittings, etc.);
  • minimum viscosity of the resulting solution;
  • good lubricity of the mixture;
  • inertness of the mixture to foaming (affects the efficiency of the circulation pump);
  • the mixture is harmless to humans and the environment.

All other things being equal, glycerin coolant has the highest viscosity - therefore, due to the increased total hydraulic resistance The heating system will require a more powerful circulation pump. In addition, glycerin-based antifreeze for heating systems has increased corrosive activity, which leads to the use of ready-made compounds with specially introduced anti-corrosion additives. Compositions based on ethylene glycol now usually have a “bad reputation”, although their viscosity is minimal and from the figures given above it is obvious that they are quite safe in use - if you do not splash around in liquids with ethylene glycol and do not take them orally in glasses. In terms of the totality of technical parameters, glycerin antifreeze for heating systems is not the best, although it usually leads in cheapness.

To recap: in the resulting dilemma of “should I use propylene glycol or glycerin for heating as antifreeze?” The final price usually plays a decisive role, since propylene glycol compounds have the best overall technical specifications have higher prices.